iOS - Skydrive Pro
Currently, there is no app for Skydrive Pro. Skydrive Pro is what you are using with Office 365. There is a "Skydrive" app out, but that is the stand alone app for Skydrive that goes with outlook.com (Old Hotmail). This app has nothing to do with Skydrive Pro or Office 365 and will not connect.
Please do a internet search on "SkyDrive vs Skydrive Pro" to better understand the differences. Once the Skydrive Pro App is released, we will update this guide.
Rumors are its coming later this year (2013)